Issue 43, 2014
From the journal:

Dalton Transactions

Crystal transformation synthesis of a highly stable fluorescent 3D indium-tetranuclear {In4(μ2-OH)3} building block based metal organic framework through a dinuclear complex†

Xin-Ming Wang,a   Rui-Qing Fan,*a   Liang-Sheng Qiang,a   Ping Wang,a   Yu-Lin Yang*a  and  Yu-Lei Wangb  

* Corresponding authors

a Department of Chemistry, Harbin Institute of Technology, Harbin 150001, P. R. China
E-mail: fanruiqing@hit.edu.cn, ylyang@hit.edu.cn
Fax: +86-451-86418270

b National Key Laboratory of Science and Technology on Tunable Laser, Harbin Institute of Technology, Harbin 150080, P. R. China

Abstract

A rare 3D tetranuclear {In4(μ2-OH)3} building block based MOF {[In4/3(μ2-OH)(2,6-pydc)(1,4-bda)0.5(H2O)]·2H2O}n (2) was obtained through a crystal transformation from a dimeric complex In3(2,6-pydc)3(1,4-bda)1.5(H2O)6 (1). With a 2D + 3D → 3D compact structure, 2 retains crystallinity in boiling water and organic solvents, exhibiting exceptional fluorescence quenching behaviour for the DMSO molecule.

Graphical abstract: Crystal transformation synthesis of a highly stable fluorescent 3D indium-tetranuclear {In4(μ2-OH)3} building block based metal organic framework through a dinuclear complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4DT02045F
Article type
Communication
Submitted
07 Jul 2014
Accepted
25 Jul 2014
First published
28 Jul 2014

Dalton Trans., 2014,43, 16152-16155

Permissions

Request permissions

Crystal transformation synthesis of a highly stable fluorescent 3D indium-tetranuclear {In4(μ2-OH)3} building block based metal organic framework through a dinuclear complex

X. Wang, R. Fan, L. Qiang, P. Wang, Y. Yang and Y. Wang, Dalton Trans., 2014, 43, 16152 DOI: 10.1039/C4DT02045F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements