Issue 32, 2014

Photoelectric conversion at a [Ru(bpy)3]2+-based metallic triad anchored on ITO surface

Abstract

A tri-metallic triad based on a [Ru(bpy)3]2+ moiety connected to Fe(II) and Co(III) bisterpyridine has been grafted on an ITO electrode by a stepwise procedure. Under visible light, in the presence of a sacrificial electron donor, the system produces electric current. The photo-current magnitude is compared to the one generated from a Co(III)–Ru(II) dyad and shows an increase of 40%.

Graphical abstract: Photoelectric conversion at a [Ru(bpy)3]2+-based metallic triad anchored on ITO surface

Supplementary files

Article information

Article type
Communication
Submitted
23 Jun 2014
Accepted
30 Jun 2014
First published
01 Jul 2014

Dalton Trans., 2014,43, 12156-12159

Author version available

Photoelectric conversion at a [Ru(bpy)3]2+-based metallic triad anchored on ITO surface

R. Farran, D. Jouvenot, F. Loiseau, J. Chauvin and A. Deronzier, Dalton Trans., 2014, 43, 12156 DOI: 10.1039/C4DT01884B

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