Issue 7, 2014

Structural and magnetic conformation of a cerocene [Ce(COT′′)2] exhibiting a uniconfigurational f1 ground state and slow-magnetic relaxation

Abstract

Magnet-like behaviour, in the form of slow relaxation of the magnetization, was observed for a monometallic cerium(III) sandwich complex. The use of trimethylsilyl substituted COT ligands (COT′′) led to the formation of a staggered COT′′ arrangement in the cerocene-type sandwich complex with a well-defined oxidation state of +3 for the Ce ion.

Graphical abstract: Structural and magnetic conformation of a cerocene [Ce(COT′′)2]− exhibiting a uniconfigurational f1 ground state and slow-magnetic relaxation

Supplementary files

Article information

Article type
Communication
Submitted
21 Nov 2013
Accepted
11 Dec 2013
First published
11 Dec 2013

Dalton Trans., 2014,43, 2737-2740

Author version available

Structural and magnetic conformation of a cerocene [Ce(COT′′)2] exhibiting a uniconfigurational f1 ground state and slow-magnetic relaxation

J. J. Le Roy, I. Korobkov, J. E. Kim, E. J. Schelter and M. Murugesu, Dalton Trans., 2014, 43, 2737 DOI: 10.1039/C3DT53280A

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