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Issue 9, 2014
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Exploring energy transfer in luminescent heterometallic ruthenium–iridium ion pairs

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Abstract

Here, we report the synthesis of a luminescent ion pair with the formula [Ru(dtBubpy)3][Ir(ppy)2(CN)2]2. The crystal structure of this three component, heterometallic assembly is described, along with the luminescence properties of the salt. The modulation of the energy transfer between the blue-green-emitting iridium complex and the red-emitting ruthenium complex is also discussed as a function of both medium and concentration.

Graphical abstract: Exploring energy transfer in luminescent heterometallic ruthenium–iridium ion pairs

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Publication details

The article was received on 08 Nov 2013, accepted on 16 Dec 2013 and first published on 17 Dec 2013


Article type: Paper
DOI: 10.1039/C3DT53170H
Citation: Dalton Trans., 2014,43, 3676-3680
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    Exploring energy transfer in luminescent heterometallic ruthenium–iridium ion pairs

    M. Sandroni and E. Zysman-Colman, Dalton Trans., 2014, 43, 3676
    DOI: 10.1039/C3DT53170H

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