Molybdenum dinitrogen complexes supported by a silicon-centred tripod ligand and dppm or dmpm: tuning the activation of N2

Henning Broda; Svea Hinrichsen; Jan Krahmer; Christian Näther; Felix Tuczek

doi:10.1039/C3DT52965G

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Molybdenum dinitrogen complexes supported by a silicon-centred tripod ligand and dppm or dmpm: tuning the activation of N₂†

Henning Broda,^a Svea Hinrichsen,^a Jan Krahmer,^a Christian Näther^a and Felix Tuczek*^a

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* Corresponding authors

^a Christian-Albrechts-Universität zu Kiel, Max-Eyth-Straße 2, 24118 Kiel, Germany
E-mail: ftuczek@ac.uni-kiel.de
Fax: +0049 (0)431 1520
Tel: +0049 (0)431 1410

Abstract

Two molybdenum dinitrogen complexes with a novel pentaphosphine environment have been synthesised and structurally characterised. A combination of the tripodal alkylphosphine ligand tris(dimethylphosphinomethyl)methylsilane (SiP₃) and the coligands dppm/dmpm has been employed to tune the activation of the N₂ ligand.

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Article information

DOI: https://doi.org/10.1039/C3DT52965G
Article type: Paper
Submitted: 21 Oct 2013
Accepted: 05 Nov 2013
First published: 05 Nov 2013

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Dalton Trans., 2014,43, 2007-2012

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Molybdenum dinitrogen complexes supported by a silicon-centred tripod ligand and dppm or dmpm: tuning the activation of N₂

H. Broda, S. Hinrichsen, J. Krahmer, C. Näther and F. Tuczek, Dalton Trans., 2014, 43, 2007 DOI: 10.1039/C3DT52965G

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Dalton Transactions