Issue 9, 2014
From the journal:

Dalton Transactions

Intramolecular excimer formation in hexakis(pyrenyloxy)cyclotriphosphazene: photophysical properties, crystal structure, and theoretical investigation†

Serkan Yeşilot,*a   Bünyemin Çoşut,a   Hüsnüye Ardıç Alidağı,a   Ferda Hacıvelioğlu,a   Gül Altınbaş Özpınar*b  and  Adem Kılıça  

* Corresponding authors

a Department of Chemistry, Gebze Institute of Technology, P.O. Box: 141, Gebze 41400, Kocaeli, Turkey
E-mail: yesil@gyte.edu.tr
Fax: +90 262 6053101
Tel: +90 262 6053137

b Department of Chemistry Technology, Biga Vocational School, Çanakkale Onsekiz Mart University, Biga 17200, Çanakkale, Turkey
E-mail: galtinbas@gmail.com, gul.ozpinar@comu.edu.tr
Fax: +90 286 3163733
Tel: +90 286 3162878

Abstract

A hexakis(pyrenyloxy)cyclotriphosphazene is synthesized by the reaction of N3P3Cl6 with 2-hydroxypyrene, and its excimer emission through intramolecular interactions in solution and in the solid state has been investigated by fluorescence spectroscopy and X-ray crystallography. Thermal and electrochemical properties were investigated. A DFT benchmark study has been performed to evaluate the intramolecular interactions and molecular orbital levels by comparing with the experimental results.

Graphical abstract: Intramolecular excimer formation in hexakis(pyrenyloxy)cyclotriphosphazene: photophysical properties, crystal structure, and theoretical investigation

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Article information

DOI
https://doi.org/10.1039/C3DT52957F
Article type
Communication
Submitted
20 Oct 2013
Accepted
03 Jan 2014
First published
07 Jan 2014

Dalton Trans., 2014,43, 3428-3433

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Intramolecular excimer formation in hexakis(pyrenyloxy)cyclotriphosphazene: photophysical properties, crystal structure, and theoretical investigation

S. Yeşilot, B. Çoşut, H. A. Alidağı, F. Hacıvelioğlu, G. A. Özpınar and A. Kılıç, Dalton Trans., 2014, 43, 3428 DOI: 10.1039/C3DT52957F

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