Abstract
A Sc NHC complex readily activates three equivalents of CO2 showing ‘Frustrated Lewis Pair’ type reactivity with each metal–carbene bond, but whilst CS2 is also activated by the labile carbenes, no metal involvement is observed.
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* Corresponding authors
a
EaStCHEM School of Chemistry, University of Edinburgh, The King's Buildings, Edinburgh, UK
E-mail:
polly.arnold@ed.ac.uk
b School of Forensic and Investigative Sciences, The University of Central Lancashire, Preston, UK
c Sasol Technology UK, Purdie Building, North Haugh, St Andrews, UK
A Sc NHC complex readily activates three equivalents of CO2 showing ‘Frustrated Lewis Pair’ type reactivity with each metal–carbene bond, but whilst CS2 is also activated by the labile carbenes, no metal involvement is observed.
P. L. Arnold, I. A. Marr, S. Zlatogorsky, R. Bellabarba and R. P. Tooze, Dalton Trans., 2014, 43, 34 DOI: 10.1039/C3DT52762J
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