A porous sodalite-type MOF based on tetrazolcarboxylate ligands and [Cu4Cl]7+ squares with open metal sites for gas sorption†
Abstract
A porous sodalite-type metal–organic framework based on tetrazolcarboxylate ligands and [Cu4Cl]7+ squares was successfully synthesized, which exhibited permanent porosity and high adsorption abilities of H2, CO2 and organic chemical pollutants.