Issue 6, 2014

Mono lacunary phosphomolybdate supported on MCM-41: synthesis, characterization and solvent free aerobic oxidation of alkenes and alcohols

Abstract

A new catalyst comprising monolacunary phosphomolybdate and MCM-41 was synthesized and characterized by different physicochemical techniques. The catalytic activity was evaluated by carrying out solvent free aerobic oxidation of alkenes and alcohols. The catalyst showed 60% conversion of styrene and 28% conversion of benzyl alcohol. The superiority of the present catalytic system lies in obtaining better conversion under solvent free and aerobic conditions.

Graphical abstract: Mono lacunary phosphomolybdate supported on MCM-41: synthesis, characterization and solvent free aerobic oxidation of alkenes and alcohols

Article information

Article type
Paper
Submitted
30 Aug 2013
Accepted
14 Nov 2013
First published
19 Nov 2013

Dalton Trans., 2014,43, 2512-2520

Mono lacunary phosphomolybdate supported on MCM-41: synthesis, characterization and solvent free aerobic oxidation of alkenes and alcohols

N. Narkhede, A. Patel and S. Singh, Dalton Trans., 2014, 43, 2512 DOI: 10.1039/C3DT52395K

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