Issue 8, 2014
From the journal:

Dalton Transactions

Fast magnetic relaxation in an octahedral dysprosium tetramethyl-aluminate complex†

Sonja N. König,a   Nicholas F. Chilton,b   Cäcilia Maichle-Mössmer,a   Eufemio Moreno Pineda,b   Thomas Pugh,b   Reiner Anwander*a  and  Richard A. Layfield*b  

* Corresponding authors

a Institut für Anorganische Chemie, Universität Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen, Germany
E-mail: Reiner.Anwander@uni-tuebingen.de

b School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK
E-mail: Richard.Layfield@manchester.ac.uk

Abstract

Ab initio calculations on the octahedral dysprosium aluminate complex [Dy(AlMe4)3] (1) predict weak SMM properties. Dynamic magnetic susceptibility measurements on 1 confirm the theoretical predictions, revealing fast relaxation of the magnetization via quantum tunnelling.

Graphical abstract: Fast magnetic relaxation in an octahedral dysprosium tetramethyl-aluminate complex

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Article information

DOI
https://doi.org/10.1039/C3DT52337C
Article type
Communication
Submitted
26 Aug 2013
Accepted
30 Sep 2013
First published
30 Sep 2013

Dalton Trans., 2014,43, 3035-3038

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Fast magnetic relaxation in an octahedral dysprosium tetramethyl-aluminate complex

S. N. König, N. F. Chilton, C. Maichle-Mössmer, E. M. Pineda, T. Pugh, R. Anwander and R. A. Layfield, Dalton Trans., 2014, 43, 3035 DOI: 10.1039/C3DT52337C

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