Issue 1, 2014
From the journal:

Dalton Transactions

Iron catalysed nitrosation of olefins to oximes†

Ritwika Ray,a   Abhishek Dutta Chowdhury,a   Debabrata Maiti*a  and  Goutam Kumar Lahiri*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Bombay, Powai, India
E-mail: lahiri@chem.iitb.ac.in, dmaiti@chem.iitb.ac.in

Abstract

Fe(BF4)2·6H2O/2,6-pyridinedicarboxylic acid catalysed nitrosation of a wide variety of substituted styrenes has been developed in the presence of t-BuONO/NaBH4 under H2 pressure (10 bar) in MeOH–H2O (5 : 1) to afford corresponding oximes in good to excellent yields.

Graphical abstract: Iron catalysed nitrosation of olefins to oximes

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Article information

DOI
https://doi.org/10.1039/C3DT51764K
Article type
Communication
Submitted
01 Jul 2013
Accepted
14 Oct 2013
First published
14 Oct 2013

Dalton Trans., 2014,43, 38-41

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Iron catalysed nitrosation of olefins to oximes

R. Ray, A. D. Chowdhury, D. Maiti and G. K. Lahiri, Dalton Trans., 2014, 43, 38 DOI: 10.1039/C3DT51764K

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