Issue 46, 2013

A 3d–4f heterometallic 3D POMOF based on lacunary Dawson polyoxometalates

Abstract

A novel compound, Na2[Ce4(H2O)22(dpdo)5](Mn2HP2W15O56)2·8H2O (1) (dpdo = 4,4′-bipyridine-N,N′-dioxide) with 3d–4f heterometallic 3D POMOF that can be described as a self-penetrating (4,4,6)-connected net topology, has been isolated via a stepwise method, and its magnetic and electrocatalytic properties have been investigated.

Graphical abstract: A 3d–4f heterometallic 3D POMOF based on lacunary Dawson polyoxometalates

Supplementary files

Article information

Article type
Paper
Submitted
22 Jul 2013
Accepted
09 Sep 2013
First published
09 Sep 2013

Dalton Trans., 2013,42, 16328-16333

A 3d–4f heterometallic 3D POMOF based on lacunary Dawson polyoxometalates

T. Yu, H. Ma, C. Zhang, H. Pang, S. Li and H. Liu, Dalton Trans., 2013, 42, 16328 DOI: 10.1039/C3DT51983J

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