Issue 34, 2013
From the journal:

Dalton Transactions

A new type of paddle-wheel coordination complex†

Leoní A. Barrios,a   Ivana Borilovic,a   Jorge Salinas Uber,a   David Aguilà,a   Olivier Roubeaub  and  Guillem Aromí*a  

* Corresponding authors

a Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain
E-mail: guillem.aromi.qi.ub.es
Tel: +34 934039760

b Instituto de Ciencia de Materiales de Aragón (ICMA), CSIC and Universidad de Zaragoza, Plaza San Francisco s/n, Zaragoza, Spain

Abstract

In the presence of Na+ ions, the reaction of the ligand 2-hydroxy-1,3-bis-(3-oxo-3-(2-hydroxyphenyl)-propionyl)-benzene, H5L4, with M(AcO)2 salts (M = Mn, Co) gathers the conditions for the assembly of coordination complexes (NBu4)3[M2Na2(H2L4)3] (M = Mn(II) 1 and Co(II) 2), which exhibit a new paddle-wheel structure. The features of this new category of compounds are discussed as well as their magnetic properties and solution behaviour.

Graphical abstract: A new type of paddle-wheel coordination complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3DT51232K
Article type
Paper
Submitted
10 May 2013
Accepted
20 Jun 2013
First published
21 Jun 2013

Dalton Trans., 2013,42, 12185-12192

Permissions

Request permissions

A new type of paddle-wheel coordination complex

L. A. Barrios, I. Borilovic, J. Salinas Uber, D. Aguilà, O. Roubeau and G. Aromí, Dalton Trans., 2013, 42, 12185 DOI: 10.1039/C3DT51232K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements