Issue 30, 2013

Formation of a 1D-polymeric chain of Hg building blocks through C–C coupling under ambient conditions

Abstract

A novel C–C coupled 1D-polymeric chain (1) is obtained by reaction of HgCl2 and hmp-H (2-(2-hydroxymethyl pyridine)) (1 : 1) in MeOH at ambient temperature. However, a new class of μ-oxo and μ-chloro bridged polymers (2) has been obtained by altering the metal : ligand ratio to 1 : 2.

Graphical abstract: Formation of a 1D-polymeric chain of Hg building blocks through C–C coupling under ambient conditions

Supplementary files

Article information

Article type
Communication
Submitted
08 May 2013
Accepted
03 Jun 2013
First published
05 Jun 2013

Dalton Trans., 2013,42, 10687-10689

Formation of a 1D-polymeric chain of Hg building blocks through C–C coupling under ambient conditions

S. M. Mobin, V. Mishra, P. Ram, A. Birla and P. Mathur, Dalton Trans., 2013, 42, 10687 DOI: 10.1039/C3DT51213D

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