Issue 31, 2013

Do planar tetracoordinate tin complexes really exist?

Abstract

New experimental and theoretical data show that the previously reported planar tetracoordinate Sn complexes [Sn(Ph2P(Se)N(Se)PPh2)2] (1-sq) and [Sn(iPr2P(Se)N(Se)PiPr2)2] (2-sq) were not isolated and rather confused with the selenium complexes [Se(Ph2P(Se)N(Se)PPh2)2] (3-sq) and [Se(iPr2P(Se)N(Se)PiPr2)2] (4-sq), respectively.

Graphical abstract: Do planar tetracoordinate tin complexes really exist?

Supplementary files

Article information

Article type
Paper
Submitted
09 Apr 2013
Accepted
29 May 2013
First published
03 Jun 2013

Dalton Trans., 2013,42, 11180-11185

Do planar tetracoordinate tin complexes really exist?

E. Rufino-Felipe, E. Osorio, G. Merino and M. Muñoz-Hernández, Dalton Trans., 2013, 42, 11180 DOI: 10.1039/C3DT50943E

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