Issue 35, 2013
From the journal:

Dalton Transactions

Synthesis and characterization of conjugated Dawson-type polyoxometalate–porphyrin copolymers†

Iban Azcarate,abc   Iftikhar Ahmed,d   Rana Farha,ef   Michel Goldmann,eg   Xiaoxia Wang,h   Hualong Xu,h   Bernold Hasenknopf,*a   Emmanuel Lacôte*bi  and  Laurent Ruhlmann*cd  

* Corresponding authors

a UPMC Univ Paris 6, Institut Parisien de Chimie Moléculaire, CNRS UMR 7201, 4 Place Jussieu, 75005 Paris, France
E-mail: bernold.hasenknopf@upmc.fr

b ICSN CNRS, Av. de la Terrasse, 91198 Gif-sur-Yvette Cedex, France

c Université de Strasbourg, Laboratoire d'Electrochimie et de Chimie Physique du Corps Solide, Institut de Chimie, 4 rue Blaise Pascal CS 90032, F-67081 Strasbourg Cedex, France
E-mail: lruhlmann@unistra.fr

d Université Paris-Sud 11, Laboratoire de Chimie Physique, U.M.R. 8000 CNRS, Bâtiment 349, 91405 Orsay cedex, France

e UPMC Univ Paris 6, Institut des NanoSciences de Paris, CNRS UMR 7588, 4 place Jussieu, 75005 Paris, France

f Laboratoire d'Analyse et Contrôle des Systèmes Complexes - LACSC-ECE Paris Ecole d'Ingénieurs, 37 Quai de Grenelle, F - 75015 Paris, France

g Université Paris Descartes, 45 rue des Saints Pères, F - 75006 Paris, France

h Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials and Laboratory of Advanced Materials, Fudan University, Shanghai 200433, People's Republic of China

i Université de Lyon, Institut de chimie de Lyon, UMR 5265 CNRS-Université Lyon I-ESCPE Lyon, 43 Bd du 11 novembre 1918, 69616 Villeurbanne, France
E-mail: emmanuel.lacote@univ-lyon1.fr

Abstract

Hybrid polyoxometalate–porphyrin copolymeric films were obtained by the electro-oxidation of zinc octaethylporphyrin (ZnOEP) in the presence of a Dawson type polyoxophosphovanadotungstate bearing two pyridyl groups (POM(py)2). The synthesis of a series of POM(py)2 consisting of [P2W15V3O62]9− functionalized with diol-amide or triol moieties, as well as the characterization of the copolymers are presented.

Graphical abstract: Synthesis and characterization of conjugated Dawson-type polyoxometalate–porphyrin copolymers

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Article information

DOI
https://doi.org/10.1039/C3DT50850A
Article type
Paper
Submitted
29 Mar 2013
Accepted
30 Apr 2013
First published
03 May 2013

Dalton Trans., 2013,42, 12688-12698

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Synthesis and characterization of conjugated Dawson-type polyoxometalate–porphyrin copolymers

I. Azcarate, I. Ahmed, R. Farha, M. Goldmann, X. Wang, H. Xu, B. Hasenknopf, E. Lacôte and L. Ruhlmann, Dalton Trans., 2013, 42, 12688 DOI: 10.1039/C3DT50850A

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