Jump to main content
Jump to site search

Issue 26, 2013
Previous Article Next Article

Structural changes within the alkaline earth uranyl phosphites

Author affiliations

Abstract

Three new alkaline earth (AE) uranyl phosphites and one barium uranium(IV) phosphate were synthesized under hydrothermal conditions. The carbonate salts of the AE's were employed both as cation sources and as pH regulators. Despite having very similar formulas and uranyl building units, the Ca2+, Sr2+ and Ba2+ uranyl phosphites have three different extended networks. The calcium compound also contains a Ca2+/UO22+ mixed cation position. The four structure types will be presented herein with the AE cations generating distinct structural transformations.

Graphical abstract: Structural changes within the alkaline earth uranyl phosphites

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 21 Mar 2013, accepted on 02 May 2013 and first published on 15 May 2013


Article type: Paper
DOI: 10.1039/C3DT50769F
Citation: Dalton Trans., 2013,42, 9637-9644
  •   Request permissions

    Structural changes within the alkaline earth uranyl phosphites

    E. M. Villa, J. Diwu, E. V. Alekseev, W. Depmeier and T. E. Albrecht-Schmitt, Dalton Trans., 2013, 42, 9637
    DOI: 10.1039/C3DT50769F

Search articles by author