Issue 16, 2013
From the journal:

Dalton Transactions

Enhancing the electronic coupling in a cyclometalated bisruthenium complex by using the 1,3,6,8-tetra(pyridin-2-yl)carbazole bridge†

Lei Wang,ab   Wen-Wen Yang,a   Yu-Wu Zhong*a  and  Jiannian Yao*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

b University of Chinese Academy of Sciences, Beijing 100049, China
E-mail: zhongyuwu@iccas.ac.cn, jnyao@iccas.ac.cn
Fax: +86-10-62559373
Tel: +86-10-62652950

Abstract

A cyclometalated bisruthenium complex bridged by the 2,7-bisdeprotonated form of 1,3,6,8-tetra(pyridin-2-yl)-9-butyl-9H-carbazole displays appreciably enhanced electronic coupling relative to that with the 5,5′-bisdeprotonated form of 3,3′,5,5′-tetra(pyridin-2-yl)-biphenyl as the bridge.

Graphical abstract: Enhancing the electronic coupling in a cyclometalated bisruthenium complex by using the 1,3,6,8-tetra(pyridin-2-yl)carbazole bridge

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Article information

DOI
https://doi.org/10.1039/C3DT50486G
Article type
Communication
Submitted
31 Jan 2013
Accepted
26 Feb 2013
First published
26 Feb 2013

Dalton Trans., 2013,42, 5611-5614

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Enhancing the electronic coupling in a cyclometalated bisruthenium complex by using the 1,3,6,8-tetra(pyridin-2-yl)carbazole bridge

L. Wang, W. Yang, Y. Zhong and J. Yao, Dalton Trans., 2013, 42, 5611 DOI: 10.1039/C3DT50486G

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