Issue 30, 2013
From the journal:

Dalton Transactions

Iron fluorophosphates†

Adam C. Keates,a   Jennifer A. Armstronga  and  Mark T. Weller*b  

* Corresponding authors

a School of Chemistry, University of Southampton, Highfield Campus, Southampton, Hampshire, UK

b Department of Chemistry, University of Bath, Bath BA2 7AY, UK
E-mail: m.t.weller@bath.ac.uk
Tel: +44 (0)1225 386531

Abstract

18 new iron fluorophosphates and a chlorofluorophosphate have been synthesised hydrothermally in a fluoride-rich medium, using FeF2, FeF3, Fe, HPF6. HCl, monovalent metal fluorides as reactants and amines as templating agents. Products have been fully structurally characterised using single crystal X-ray diffraction, and the stability of some compounds investigated using thermogravimetric analysis. Reaction in fluoride-rich conditions produce ribbon-like, layer and framework structures containing new and unusual structural motifs based on the linking of Fe(O,F)6, PO3F, and PO2(OH,F)2 polyhedra. Structures exhibiting inter-layer spaces and channels are frequently lined by terminal fluoride anions of the PO3F, PO2(OH,F)2 and Fe(O,F)6 polyhedra.

Graphical abstract: Iron fluorophosphates

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Article information

DOI
https://doi.org/10.1039/C3DT50324K
Article type
Paper
Submitted
17 Jan 2013
Accepted
04 Jun 2013
First published
05 Jun 2013

Dalton Trans., 2013,42, 10715-10724

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Iron fluorophosphates

A. C. Keates, J. A. Armstrong and M. T. Weller, Dalton Trans., 2013, 42, 10715 DOI: 10.1039/C3DT50324K

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