Octamolybdate-supported tricarbonyl metal derivatives: [{H2Mo8O30}{M(CO)3}2]8− (M = MnI and ReI)

Dongdi Zhang; Juan Zhao; Yanhui Zhang; Xiaojing Hu; Longsheng Li; Pengtao Ma; Jingping Wang; Jingyang Niu

doi:10.1039/C2DT32678G

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Octamolybdate-supported tricarbonyl metal derivatives: [{H₂Mo₈O₃₀}{M(CO)₃}₂]⁸⁻ (M = Mn^I and Re^I)†

Dongdi Zhang,^a Juan Zhao,^b Yanhui Zhang,^b Xiaojing Hu,^a Longsheng Li,^a Pengtao Ma,^b Jingping Wang*^ab and Jingyang Niu*^ab

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* Corresponding authors

^a Polyoxometalates Chemistry Key Laboratory of Henan Province, Henan University, Kaifeng, China
E-mail: jyniu@henu.edu.cn
Fax: (+86) 378 3886876
Tel: (+86) 378 3886876

^b Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, China
E-mail: jpwang@henu.edu.cn
Fax: (+86) 378 3886876
Tel: (+86) 378 3886876

Abstract

Two novel octamolybdate-based tricarbonyl metal derivatives have been successfully synthesized and characterized, which represent the first two examples of tricarbonyl metal groups attached to a new {Mo₈O₃₀} building block.

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Article information

DOI: https://doi.org/10.1039/C2DT32678G
Article type: Communication
Submitted: 09 Nov 2012
Accepted: 03 Jan 2013
First published: 07 Jan 2013

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Dalton Trans., 2013,42, 2696-2699

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Octamolybdate-supported tricarbonyl metal derivatives: [{H₂Mo₈O₃₀}{M(CO)₃}₂]⁸⁻ (M = Mn^I and Re^I)

D. Zhang, J. Zhao, Y. Zhang, X. Hu, L. Li, P. Ma, J. Wang and J. Niu, Dalton Trans., 2013, 42, 2696 DOI: 10.1039/C2DT32678G

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Dalton Transactions