Novel single-crystal's voltage-dependent effect and magnetic order of Ln2ZrQ5 (Ln = La, Sm, Gd; Q = S, Se) semiconductors

Sheng-Ping Guo; Guan-E Wang; Ming-Jian Zhang; Mei-Feng Wu; Guang-Ning Liu; Xiao-Ming Jiang; Guo-Cong Guo; Jin-Shun Huang

doi:10.1039/C2DT32321D

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Novel single-crystal's voltage-dependent effect and magnetic order of Ln₂ZrQ₅ (Ln = La, Sm, Gd; Q = S, Se) semiconductors†

Sheng-Ping Guo,^a Guan-E Wang,^a Ming-Jian Zhang,^a Mei-Feng Wu,^a Guang-Ning Liu,^a Xiao-Ming Jiang,^a Guo-Cong Guo*^a and Jin-Shun Huang^a

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* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: gcguo@fjirsm.ac.cn
Fax: +86 591 83714946

Abstract

A series of rare-earth zirconium chalcogenides Ln₂ZrQ₅ (Ln = La, Sm, Gd; Q = S, Se) synthesized by using boron as the reducing reagent show unprecedented single-crystal's intrinsic voltage-dependent effects and order antiferromagnetically.

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Article information

DOI: https://doi.org/10.1039/C2DT32321D
Article type: Communication
Submitted: 02 Oct 2012
Accepted: 18 Dec 2012
First published: 19 Dec 2012

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Dalton Trans., 2013,42, 2679-2682

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Novel single-crystal's voltage-dependent effect and magnetic order of Ln₂ZrQ₅ (Ln = La, Sm, Gd; Q = S, Se) semiconductors

S. Guo, G. Wang, M. Zhang, M. Wu, G. Liu, X. Jiang, G. Guo and J. Huang, Dalton Trans., 2013, 42, 2679 DOI: 10.1039/C2DT32321D

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