Issue 2, 2013

A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands

Abstract

Addition of [Mo2VO2(μ-O)(μ-S)(aq)]2+ linker-type units to a solution/dynamic library containing tungstates results via the formation of the complementary pentagonal {(W)W5} units logically in the self-assembly of a mixed oxide/sulphide {WVI72MoV60}-type Keplerate, thereby demonstrating the ability to tune the capsule's skeletal softness (the (μ-O)2 and (μ-S)2 scenarios are known) and providing options to influence differently important capsule–substrate interactions.

Graphical abstract: A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands

Supplementary files

Article information

Article type
Communication
Submitted
25 Sep 2012
Accepted
29 Oct 2012
First published
29 Oct 2012

Dalton Trans., 2013,42, 330-333

A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands

C. Schäffer, A. M. Todea, H. Bögge, S. Floquet, E. Cadot, V. S. Korenev, V. P. Fedin, P. Gouzerh and A. Müller, Dalton Trans., 2013, 42, 330 DOI: 10.1039/C2DT32247A

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