Issue 47, 2012
From the journal:

Dalton Transactions

Low melting Li/K/Cs acetate salt mixtures as new ionic media for catalytic applications – first physico-chemical characterization

Stephanie Bajus,a   Alexey Deyko,b   Andreas Bösmann,a   Florian Maier,b   Hans-Peter Steinrückb  and  Peter Wasserscheid*a  

* Corresponding authors

a Institute of Chemical Reaction Engineering, University of Erlangen-Nuremberg, Egerlandstr. 3, 91058 Erlangen, Germany
E-mail: peter.wasserscheid@crt.cbi.uni-erlangen.de
Fax: (+49)9131-8527421

b Institute of Physical Chemistry II, University of Erlangen Nuremberg, Germany

Abstract

In order to expand the temperature limits of Supported Ionic Liquid Phase (SILP) or Solid Catalyst with Ionic Liquid Layer (SCILL) systems to higher operation temperatures, the mixture of lithium acetate, potassium acetate, and caesium acetate (molar ratio of 0.2/0.275/0.525) has been studied in detail. Physico-chemical properties of the bulk melt are reported together with stability data of the modern salt on various solid support materials showing attractive properties for many potential high temperature applications.

Graphical abstract: Low melting Li/K/Cs acetate salt mixtures as new ionic media for catalytic applications – first physico-chemical characterization

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Article information

DOI
https://doi.org/10.1039/C2DT31568H
Article type
Paper
Submitted
15 Jul 2012
Accepted
14 Sep 2012
First published
14 Sep 2012

Dalton Trans., 2012,41, 14433-14438

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Low melting Li/K/Cs acetate salt mixtures as new ionic media for catalytic applications – first physico-chemical characterization

S. Bajus, A. Deyko, A. Bösmann, F. Maier, H. Steinrück and P. Wasserscheid, Dalton Trans., 2012, 41, 14433 DOI: 10.1039/C2DT31568H

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