Issue 45, 2012

A planar chiral [2.2]paracyclophane derived N-heterocyclic stannylene

Abstract

The reaction of pseudo-ortho-4,12-N,N′-diphenyldiamino-[2.2]paracyclophane ((±)-3) with Sn[N(SiMe3)2]2 results in the formation of the monomeric planar chiral N-heterocyclic stannylene (±)-4, featuring a unique [2.2]paracyclophane backbone, which has been characterized by an X-ray diffraction study.

Graphical abstract: A planar chiral [2.2]paracyclophane derived N-heterocyclic stannylene

Supplementary files

Article information

Article type
Communication
Submitted
09 Jul 2012
Accepted
13 Aug 2012
First published
14 Aug 2012

Dalton Trans., 2012,41, 13788-13790

A planar chiral [2.2]paracyclophane derived N-heterocyclic stannylene

I. Piel, J. V. Dickschat, T. Pape, F. E. Hahn and F. Glorius, Dalton Trans., 2012, 41, 13788 DOI: 10.1039/C2DT31497E

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