Issue 31, 2012
From the journal:

Dalton Transactions

Axial chiral metallocenes by two-fold ring-closing metathesis†

W. Buchowicz,*a   A. Furmańczyk,a   J. Zacharaa  and  M. Majchrzakb  

* Corresponding authors

a Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, Poland
E-mail: wbuch@ch.pw.edu.pl
Fax: +48 22 234 5462
Tel: +48 22 234 5150

b Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland

Abstract

Novel doubly bridged metallocenes have been prepared by remarkably selective two-fold alkene ring-closing metathesis. The solid state structures of 3 and 5 reveal 1,2′,3,4′-connectivity and screw-shaped geometry of the molecules.

Graphical abstract: Axial chiral metallocenes by two-fold ring-closing metathesis

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Article information

DOI
https://doi.org/10.1039/C2DT31291C
Article type
Communication
Submitted
15 Jun 2012
Accepted
22 Jun 2012
First published
22 Jun 2012

Dalton Trans., 2012,41, 9269-9271

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Axial chiral metallocenes by two-fold ring-closing metathesis

W. Buchowicz, A. Furmańczyk, J. Zachara and M. Majchrzak, Dalton Trans., 2012, 41, 9269 DOI: 10.1039/C2DT31291C

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