Issue 33, 2012

A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor

Abstract

A 1,3-dipolar cycloaddition reaction taking place quantitatively between propiolic acid “guests” and azide functions previously attached to binding sites within the cavity of a {Mo132}-type Keplerate reproducibly gives a 2 : 1 ratio of 1,4- and 1,5-triazoles.

Graphical abstract: A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor

Supplementary files

Article information

Article type
Communication
Submitted
01 Mar 2012
Accepted
20 Jun 2012
First published
10 Jul 2012

Dalton Trans., 2012,41, 9852-9854

A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor

C. Besson, S. Schmitz, K. M. Capella, S. Kopilevich, I. A. Weinstock and P. Kögerler, Dalton Trans., 2012, 41, 9852 DOI: 10.1039/C2DT30502J

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