Issue 20, 2012

Tuning the wavelength of electrochemiluminescence by anodic potential: a design using non-Kekulé-structured iridium–ruthenium luminophores

Abstract

Setting up spatially separated HOMO and LUMO regions in a non-Kekulé structured trinuclear Ir(III)–Ru(II)–Ir(III) system and using oxidative-reduction electrochemiluminescence leads to emissions that are not detected in photoluminescence. Moreover, the new design allows tuning of the wavelength of emission in a stepless fashion as a function of the selected potential range.

Graphical abstract: Tuning the wavelength of electrochemiluminescence by anodic potential: a design using non-Kekulé-structured iridium–ruthenium luminophores

Supplementary files

Article information

Article type
Communication
Submitted
10 Feb 2012
Accepted
09 Mar 2012
First published
03 Apr 2012

Dalton Trans., 2012,41, 6064-6068

Tuning the wavelength of electrochemiluminescence by anodic potential: a design using non-Kekulé-structured iridium–ruthenium luminophores

M. Schmittel, Q. Shu and M. E. Cinar, Dalton Trans., 2012, 41, 6064 DOI: 10.1039/C2DT30303E

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