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Issue 18, 2012
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Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks

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Abstract

Sodalite zeolitic imidazolate frameworks containing Co (ZIF-67) and Zn (ZIF-8) were synthesized at room temperature under aqueous conditions in 10 min. A trialkylamine deprotonated the 2-methylimidazole ligand and nucleated the frameworks. Furthermore, the ligand acted as a structure directing agent in place of an organic solvent.

Graphical abstract: Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks

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Publication details

The article was received on 24 Jan 2012, accepted on 28 Feb 2012 and first published on 12 Mar 2012


Article type: Communication
DOI: 10.1039/C2DT30174A
Citation: Dalton Trans., 2012,41, 5458-5460
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    Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks

    A. F. Gross, E. Sherman and J. J. Vajo, Dalton Trans., 2012, 41, 5458
    DOI: 10.1039/C2DT30174A

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