Issue 17, 2012
From the journal:

Dalton Transactions

Synthesis, structure and reactivity of 4-phosphanylated 1,3-dialkyl-imidazole-2-thiones†

Susanne Sauerbrey,a   Paresh Kumar Majhi,a   Gregor Schnakenburg,a   Anthony J. Arduengo III*b  and  Rainer Streubel*a  

* Corresponding authors

a Institut für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhard-Domagk-Str. 1, 53121 Bonn, Germany
E-mail: r.streubel@uni-bonn.de
Fax: +49-228-73-9616

b Department of Chemistry, The University of Alabama, Tuscaloosa, AL 35487, USA
E-mail: aj@ajarduengo.net

Abstract

Selective formation of 4-phosphanylated 1,2-dialkyl imidazole-2-thiones 3a–f has been obtained via a lithiation followed by phosphanylation reaction. The reactivity of 3a–f was examined towards oxidation and complexation reactions. All products were unambiguously characterized by elemental analyses, spectroscopic and spectrometric methods including X-ray analysis (3a, 3b, 4b, 4d, 5b, 6a and 6d).

Graphical abstract: Synthesis, structure and reactivity of 4-phosphanylated 1,3-dialkyl-imidazole-2-thiones

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2DT12483A
Article type
Paper
Submitted
23 Dec 2011
Accepted
13 Feb 2012
First published
13 Feb 2012

Dalton Trans., 2012,41, 5368-5376

Permissions

Request permissions

Synthesis, structure and reactivity of 4-phosphanylated 1,3-dialkyl-imidazole-2-thiones

S. Sauerbrey, P. K. Majhi, G. Schnakenburg, A. J. Arduengo III and R. Streubel, Dalton Trans., 2012, 41, 5368 DOI: 10.1039/C2DT12483A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements