Issue 19, 2012
From the journal:

Dalton Transactions

Solvent-modulated metamagnetism in an Fe(ii) system exhibiting a two-step field-induced magnetic transition†

Chun-Ding Zhou,a   Chao Chen,a   Li-Xuan Caia  and  Jie Zhang*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: zhangjie@fjirsm.ac.cn
Fax: (+86) 591-83710051

Abstract

A one-dimensional iron(II) coordination polymer, [Fe3(hpdc)2(H2O)6]·2H2O (H3hpdc = 2-hydroxypyrimidine-4,6-dicarboxylic acid) has been synthesized and characterized. The compound exhibits field-induced two-step magnetic phase transitions and a coexistence of spin-canting and metamagnetism, and undergoes a structural transformation from single-crystalline to amorphous state upon dehydration, accompanied by significantly enhanced spontaneous magnetization and critical temperature.

Graphical abstract: Solvent-modulated metamagnetism in an Fe(ii) system exhibiting a two-step field-induced magnetic transition

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Article information

DOI
https://doi.org/10.1039/C2DT12260J
Article type
Paper
Submitted
25 Nov 2011
Accepted
07 Mar 2012
First published
03 Apr 2012

Dalton Trans., 2012,41, 5912-5918

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Solvent-modulated metamagnetism in an Fe(II) system exhibiting a two-step field-induced magnetic transition

C. Zhou, C. Chen, L. Cai and J. Zhang, Dalton Trans., 2012, 41, 5912 DOI: 10.1039/C2DT12260J

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