Issue 3, 2012
From the journal:

Dalton Transactions

Synthesis and structure of QD-6: A novel aluminoborate constructed from unprecedented [B@Al6O24] and polyborate clusters†

Guo-Ming Wang,*a   Jin-Hua Li,a   Pei Wang,a   Zeng-Xin Li,a   Ying-Xia Wang,*b   Zhe-Ming Wangb  and  Jian-Hua Linb  

* Corresponding authors

a Teachers College, College of Chemistry, Chemical Engineering and Environment of Qingdao University, Shandong, China
E-mail: gmwang_pub@163.com

b Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing, China
E-mail: wangyx@pku.edu.cn

Abstract

A novel aluminoborate (NH4)6[C5NH12]6[Al12B65O105(OH)33]·(H2O)15 (QD-6), has been synthesized under mild hydrothermal conditions and characterized by IR, elemental analysis, TGA, powder and single-crystal X-ray diffractions. This compound crystallizes in the rhombohedral space group[R with combining macron]3 (No. 148) with the lattice constants a = 23.7421(2) Å, c = 24.7699(3) Å, V = 12091.9(2) Å3, and Z = 3. QD-6 consists of two unprecedented aluminoborate clusters, [Al6B34O54(OH)18]6− and [Al6B31O51(OH)15]6−, which are built from the same hexagon-like [B@Al6O24] clusters and [B11O17(OH)6] or [B10O16(OH)5] polyborates.

Graphical abstract: Synthesis and structure of QD-6: A novel aluminoborate constructed from unprecedented [B@Al6O24] and polyborate clusters

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Article information

DOI
https://doi.org/10.1039/C1DT11929J
Article type
Communication
Submitted
13 Oct 2011
Accepted
15 Nov 2011
First published
29 Nov 2011

Dalton Trans., 2012,41, 734-736

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Synthesis and structure of QD-6: A novel aluminoborate constructed from unprecedented [B@Al6O24] and polyborate clusters

G. Wang, J. Li, P. Wang, Z. Li, Y. Wang, Z. Wang and J. Lin, Dalton Trans., 2012, 41, 734 DOI: 10.1039/C1DT11929J

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