Issue 41, 2011

Unique Pt5 metallacycle: [PtIICl(pyrrolidinedithiocarbamate)]5

Abstract

The neutral complex [PtCl(PyDT)]5 (PyDT = (CH2)4NCS2) represents the first example of a Pt5 metallacycle. This unique architecture based on chiral S-bridged PtII monomers was prepared by thermal degradation of the reaction product of PtCl2 and a pyrrolidinedithioester.

Graphical abstract: Unique Pt5 metallacycle: [PtIICl(pyrrolidinedithiocarbamate)]5

Supplementary files

Article information

Article type
Communication
Submitted
29 Jun 2011
Accepted
12 Aug 2011
First published
08 Sep 2011

Dalton Trans., 2011,40, 10809-10811

Unique Pt5 metallacycle: [PtIICl(pyrrolidinedithiocarbamate)]5

D. Montagner and P. J. Sanz Miguel, Dalton Trans., 2011, 40, 10809 DOI: 10.1039/C1DT11475A

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