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Issue 41, 2011
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Unique Pt5 metallacycle: [PtIICl(pyrrolidinedithiocarbamate)]5

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Abstract

The neutral complex [PtCl(PyDT)]5 (PyDT = (CH2)4NCS2) represents the first example of a Pt5 metallacycle. This unique architecture based on chiral S-bridged PtII monomers was prepared by thermal degradation of the reaction product of PtCl2 and a pyrrolidinedithioester.

Graphical abstract: Unique Pt5 metallacycle: [PtIICl(pyrrolidinedithiocarbamate)]5

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Publication details

The article was received on 29 Jun 2011, accepted on 12 Aug 2011 and first published on 08 Sep 2011


Article type: Communication
DOI: 10.1039/C1DT11475A
Citation: Dalton Trans., 2011,40, 10809-10811
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    Unique Pt5 metallacycle: [PtIICl(pyrrolidinedithiocarbamate)]5

    D. Montagner and P. J. Sanz Miguel, Dalton Trans., 2011, 40, 10809
    DOI: 10.1039/C1DT11475A

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