Synthesis, field-emission and electric properties of metastable phase VO2 (A) ultra-long nanobelts

Abstract

High quality single crystalline metastable phase VO₂ (A) ultra-long nanobelts were synthesized by hydrothermal method using inorganic V₂O₅ sol as precursor and polyethylene glycol (PEG) as both surfactant and reducing agent. It was found that the oriented attach growth mechanism is responsible for the formation of VO₂ (A) nanobelts. In addition to an endothermic peak, an unusual exothermic peak was detected in DSC curve of the nanobelts. The temperature dependence of the lattice parameters have been studied, and it was found that the a-axis expands while the c-axis contracts in the high-temperature XRD test. The VO₂ (A) nanobelt has a low turn-on field of 3.8 V μm⁻¹ and a high field enhancement factor of 1739 in the field emission measurement. Electrical transport measurement of a single VO₂ (A) nanobelt gives a relative low hoping activation energy of 0.28 eV.