Dynamic behaviour of Ru and Ru–Pt complexes containing tetrahedro-P4 ligand†
Abstract
Dynamic processes involving the P4 cage coordinated to transition metal fragments were observed for the mononuclear complex trans-[Ru(dppm)2(H)(η1-P4)]BF4 and for the bimetallic derivative trans-[Ru(dppm)2(H)(μ ,η1:2-P4){Pt(PPh3)2}]BF4 as demonstrated by