Issue 35, 2011
From the journal:

Dalton Transactions

A novel amphiphilic pincer palladium complex: design, preparation and self-assembling behavior†

Go Hamasaka,a   Tsubasa Mutoab  and  Yasuhiro Uozumi*abc  

* Corresponding authors

a Institute for Molecular Science, Myodaiji, Okazaki, Japan
E-mail: uo@ims.ac.jp
Fax: (+81)564-59-5574

b The Graduate School for Advanced Studies, Myoudaiji, Okazaki, Japan

c Riken, Hirosawa, Wako, Japan
E-mail: uo@riken.jp

Abstract

Amphiphilic pincer palladium complexes bearing hydrophilic and hydrophobic side chains on the planar NCN palladium pincer backbone were designed and prepared via the ligand introduction route. The complexes self-assembled under aqueous conditions to form vesicles with bilayer membranes containing palladium species. The catalytic activity of the vesicles in the Miyaura–Michael reaction in water was investigated.

Graphical abstract: A novel amphiphilic pincer palladium complex: design, preparation and self-assembling behavior

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Article information

DOI
https://doi.org/10.1039/C1DT10556F
Article type
Paper
Submitted
01 Apr 2011
Accepted
05 Jul 2011
First published
11 Aug 2011

Dalton Trans., 2011,40, 8859-8868

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A novel amphiphilic pincer palladium complex: design, preparation and self-assembling behavior

G. Hamasaka, T. Muto and Y. Uozumi, Dalton Trans., 2011, 40, 8859 DOI: 10.1039/C1DT10556F

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