Issue 21, 2011
From the journal:

Dalton Transactions

Unprecedented copper(i)-catalyzed in situ double cycloaddition reaction based on 2-cyanopyrimidine†

Tian Wen,a   Mian Li,a   Xiao-Ping Zhoua  and  Dan Li*a  

* Corresponding authors

a Department of Chemistry, Shantou University, Guangdong 515063, P. R. China
E-mail: dli@stu.edu.cn

Abstract

The solvothermal in situ double cycloaddition reaction of 2-cyanopyrimidine, Cu2O and NaN3 with aqueous ammonia additive generated a two dimensional copper(I) coordination polymer with 5-pyrimidyl-tetrazolate, 3,5-bispyrimidyl-1,2,4-triazolate and the cyano group as the ligands. This reaction can be tuned to yield two dimensional coordination polymers solely based on tetrazolate or 1,2,4-triazolate ligands.

Graphical abstract: Unprecedented copper(i)-catalyzed in situ double cycloaddition reaction based on 2-cyanopyrimidine

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Article information

DOI
https://doi.org/10.1039/C1DT10488H
Article type
Communication
Submitted
23 Mar 2011
Accepted
08 Apr 2011
First published
28 Apr 2011

Dalton Trans., 2011,40, 5684-5686

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Unprecedented copper(I)-catalyzed in situ double cycloaddition reaction based on 2-cyanopyrimidine

T. Wen, M. Li, X. Zhou and D. Li, Dalton Trans., 2011, 40, 5684 DOI: 10.1039/C1DT10488H

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