Intramolecularly coordinated heteroleptic organostannylene tungsten pentacarbonyl complexes 4-tBu-2,6-[P(O)(OiPr)2]2C6H2Sn(X)W(CO)5 (X = Cl, F, PPh2, PPh2[W(CO)5]). Syntheses and reactivity†‡
Abstract
The synthesis of the intramolecularly coordinated heteroleptic organostannylene tungsten pentacarbonyl complexes 4-tBu-2,6-[P(O)(OiPr)2]2C6H2Sn(X)W(CO)5 (1, X = Cl; 2, X = F; 3, X = PPh2) and of 4-tBu-2,6-[P(O)(OiPr)2]2C6H2Sn[W(CO)5]PPh2[W(CO)5], 4, are reported. UV-irradiation of compound 4 in
- This article is part of the themed collection: Pincers and other hemilabile ligands