Issue 17, 2011
From the journal:

Dalton Transactions

Infinite terbium(iii) chains formed from a tetra-phosphorylated resorcinarene cavitand†

Hani El Moll,a   David Sémeril,*a   Dominique Matt,*a   Loïc Charbonnière*b  and  Loïc Toupetc  

* Corresponding authors

a Laboratoire de Chimie Inorganique et Catalyse, Université de Strasbourg, Institut de Chimie de Strasbourg, UMR 7177 CNRS, 1, rue Blaise-Pascal, Strasbourg cedex, France
E-mail: dsemeril@chimie.u-strasbg.fr, dmatt@chimie.u-strasbg.fr

b Laboratoire d'Ingénierie Moléculaire Appliquée à l'Analyse, IPHC, ECPM, UMR 7178 CNRS, 25 rue Becquerel, Strasbourg Cedex, France

c Institut de Physique de Rennes, UMR 6251, Université de Rennes 1, Campus de Beaulieu, Rennes cedex, France

Abstract

Reaction of [TbIII(DMSO)8](CF3SO3)3 with a resorcinarene cavitand substituted by four –CH2P(O)Ph2 pendant arms afforded an infinite 1D inorganic polymer, in which the consecutive resorcinarene units are linked through two terbium strands, this connection involves pairs of phosphoryl groups occupying adjacent positions of the resorcinarene units.

Graphical abstract: Infinite terbium(iii) chains formed from a tetra-phosphorylated resorcinarene cavitand

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Article information

DOI
https://doi.org/10.1039/C0DT01808B
Article type
Communication
Submitted
22 Dec 2010
Accepted
23 Feb 2011
First published
14 Mar 2011

Dalton Trans., 2011,40, 4391-4393

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Infinite terbium(III) chains formed from a tetra-phosphorylated resorcinarene cavitand

H. E. Moll, D. Sémeril, D. Matt, L. Charbonnière and L. Toupet, Dalton Trans., 2011, 40, 4391 DOI: 10.1039/C0DT01808B

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