Two diphosphonate-functionalized asymmetric polyoxomolybdates with catalytic activity for oxidation of benzyl alcohol to benzaldehyde†
Abstract
Two asymmetric polyoxomolybdates Na6{Mo2O5[(Mo2O6)NH3CH2CH2CH2C(O)(PO3)2]2}·16H2O (1) and (NH4)7Na{MoO2[(Mo2O6)NH3CH2CH2CH2C(O)(PO3)2]}4·H2O (2) have been synthesized by the reactions of