Issue 10, 2011
From the journal:

Dalton Transactions

Photoreactivity of crystals of a rhodium dithionite complex with ethyltetramethylcyclopentadienyl ligands: Crystal surface morphology changes and degradation†

Hidetaka Nakai,*ab   Shinobu Uemura,c   Yousuke Miyano,a   Motohiro Mizuno,a   Masahiro Irie*d  and  Kiyoshi Isobe*ab  

* Corresponding authors

a Department of Chemistry, Graduate School of Natural Science & Technology, Kanazawa University, Kakuma-machi, Kanazawa, Japan

b Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, Japan
E-mail: nakai@mail.cstm.kyushu-u.ac.jp, isobetcm@mail.cstm.kyushu-u.ac.jp
Fax: +81 92 802 2823
Tel: +81 92 802 2822

c Department of Applied Chemistry and Biochemistry, Kumamoto University, 2-39-1 Kurokami, Kumamoto, Japan

d Department of Chemistry, Rikkyo University, Nishi-Ikebukuro 3-34-1, Toshima-ku, Tokyo, Japan
E-mail: iriem@rikkyo.ac.jp

Abstract

A photoreactive rhodium dithionite complex [(RhCpEt)2(μ-CH2)2(μ-O2SSO2)] (1Et) with CpEt (η5-C5Me4Et) ligands was newly synthesized. Upon short-time irradiation with low intensity light, two kinds of stepwise surface morphology changes of the crystal 1Et were observed. Prolonged irradiation with high intensity light caused cracking and breaking down of the crystal.

Graphical abstract: Photoreactivity of crystals of a rhodium dithionite complex with ethyltetramethylcyclopentadienyl ligands: Crystal surface morphology changes and degradation

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Article information

DOI
https://doi.org/10.1039/C0DT01645D
Article type
Communication
Submitted
26 Nov 2010
Accepted
12 Jan 2011
First published
04 Feb 2011

Dalton Trans., 2011,40, 2177-2179

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Photoreactivity of crystals of a rhodium dithionite complex with ethyltetramethylcyclopentadienyl ligands: Crystal surface morphology changes and degradation

H. Nakai, S. Uemura, Y. Miyano, M. Mizuno, M. Irie and K. Isobe, Dalton Trans., 2011, 40, 2177 DOI: 10.1039/C0DT01645D

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