Issue 11, 2011
From the journal:

Dalton Transactions

Non-innocent reactivity of bis-phosphinimine pincer ligands in palladium complexes†

Michael J. Sgroa  and  Douglas W. Stephan*a  

* Corresponding authors

a Department of Chemistry, University of Toronto, 80 St. George St. Toronto, Ontario, Canada
E-mail: dstephan@chem.utoronto.ca
Tel: 416-946-3294

Abstract

Although the Pd complex of the bis-phosphinimine pincer ligand 1,3-C6H3(CH2N[double bond, length as m-dash]PPh3)2 is accessible, this ligand is also non-innocent in the formation of a phosphinimine-aminophosphine pincer complex; as well, both complexes undergo hydride abstraction generating unique formally cationic ligand complexes.

Graphical abstract: Non-innocent reactivity of bis-phosphinimine pincer ligands in palladium complexes

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Article information

DOI
https://doi.org/10.1039/C0DT01623C
Article type
Communication
Submitted
22 Nov 2010
Accepted
04 Jan 2011
First published
14 Jan 2011

Dalton Trans., 2011,40, 2419-2421

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Non-innocent reactivity of bis-phosphinimine pincer ligands in palladium complexes

M. J. Sgro and D. W. Stephan, Dalton Trans., 2011, 40, 2419 DOI: 10.1039/C0DT01623C

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