Issue 6, 2011
From the journal:

Dalton Transactions

Oximate-substituted zirconium alkoxides†

Stefan O. Baumann,a   Michael Puchbergera  and  Ulrich Schubert*a  

* Corresponding authors

a Institute of Materials Chemistry, Vienna University of Technology, Getreidemarkt 9, Vienna, Austria
E-mail: uschuber@mail.zserv.tuwien.ac.at
Fax: +43-1-58801-16599

Abstract

The reaction of acetoxime, ethyl methyl ketoxime or cyclohexanone oxime with zirconium iso-propoxide gave dimeric alkoxo oximate derivatives [Zr(OiPr)(oximate)3]2. The oximate ligands are side-on coordinated and the alkoxo groups bridge the two metal centres. NMR spectroscopy revealed dynamic behaviour of the compounds in solution. When exposing a reaction mixture of zirconium butoxide and cyclohexanone oxime to ambient moisture, the oxo-alkoxo derivative Zr4O(OBu)8(ON[double bond, length as m-dash]C6H10)6 was obtained.

Graphical abstract: Oximate-substituted zirconium alkoxides

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0DT00384K
Article type
Paper
Submitted
28 Apr 2010
Accepted
21 Nov 2010
First published
06 Jan 2011

Dalton Trans., 2011,40, 1401-1406

Permissions

Request permissions

Oximate-substituted zirconium alkoxides

S. O. Baumann, M. Puchberger and U. Schubert, Dalton Trans., 2011, 40, 1401 DOI: 10.1039/C0DT00384K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements