Issue 40, 2010
From the journal:

Dalton Transactions

An 18+δ iridium dimer releasing metalloradicals spontaneously†

Tsun-Ren Chen,*a   Hsiu-Pen Lee,a   Jhy-Der Chenb  and  Kelvin H.-C. Chena  

* Corresponding authors

a Department of Chemical Biology, National Pingtung University of Education, Pingtung, Taiwan
E-mail: trchen@mail.npue.edu.tw
Fax: 886-8-7230305
Tel: 886-8-7226141 ext. 33258

b Department of Chemistry, Chung-Yuan Christian University, Chung-Li, Taiwan

Abstract

Reductive elimination of a bridged chlorine from a diiridium(III) core, [(dfpbo)2Ir(μ-Cl)]2 (dfpbo = 2-(3.5-difluorophenyl)benzoxazolato-N,C2), afforded an iridium dimer, [(fpbo)2Ir]2(μ-Cl), showing an 18+δ structure with a bent bridge, which can release metalloradicals spontaneously in solution at room temperature.

Graphical abstract: An 18+δ iridium dimer releasing metalloradicals spontaneously

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Article information

DOI
https://doi.org/10.1039/C0DT00605J
Article type
Communication
Submitted
04 Jun 2010
Accepted
11 Aug 2010
First published
03 Sep 2010

Dalton Trans., 2010,39, 9458-9461

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An 18+δ iridium dimer releasing metalloradicals spontaneously

T. Chen, H. Lee, J. Chen and K. H.-C. Chen, Dalton Trans., 2010, 39, 9458 DOI: 10.1039/C0DT00605J

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