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Issue 24, 2010
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DABCO-functionalized metal–organic framework bearing a C2h-symmetric terphenyl dicarboxylate linker

Ja-Min Gu,a  Tae-Hwan Kwon,a  Ji-Hyun Parka  and  Seong Huh*a 
Author affiliations

* Corresponding authors

a Department of Chemistry and Protein Research Center for Bio-Industry, Hankuk University of Foreign Studies, Yongin, Korea
E-mail: shuh@hufs.ac.kr
Fax: 82 31 330 4566
Tel: 82 31 330 4522

Abstract

A Zn-MOF assembled from a new C2h-symmetric terphenyl dicarboxylate and DABCO was prepared and characterized by X-ray crystallography and gas sorption analysis: a preferential sorption of CO2 over N2 and H2 was observed with an exceptionally high CO2 adsorption enthalpy.

Graphical abstract: DABCO-functionalized metal–organic framework bearing a C2h-symmetric terphenyl dicarboxylate linker

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Publication details

The article was received on 29 Apr 2010, accepted on 06 May 2010 and first published on 24 May 2010


Article type: Communication
DOI: 10.1039/C0DT00392A
Citation: Dalton Trans., 2010,39, 5608-5610
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    DABCO-functionalized metal–organic framework bearing a C2h-symmetric terphenyl dicarboxylate linker

    J. Gu, T. Kwon, J. Park and S. Huh, Dalton Trans., 2010, 39, 5608
    DOI: 10.1039/C0DT00392A

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