DABCO-functionalized metal–organic framework bearing a C2h-symmetric terphenyl dicarboxylate linker

Ja-Min Gu; Tae-Hwan Kwon; Ji-Hyun Park; Seong Huh

doi:10.1039/C0DT00392A

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Dalton Transactions

Issue 24, 2010

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 4.177 48 Issues per Year Indexed in Medline

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DABCO-functionalized metal–organic framework bearing a C_2h-symmetric terphenyl dicarboxylate linker

Ja-Min Gu,^a Tae-Hwan Kwon,^a Ji-Hyun Park^a and Seong Huh*^a

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Department of Chemistry and Protein Research Center for Bio-Industry, Hankuk University of Foreign Studies, Yongin, Korea
E-mail: shuh@hufs.ac.kr
Fax: 82 31 330 4566
Tel: 82 31 330 4522

Dalton Trans., 2010,39, 5608-5610

DOI: 10.1039/C0DT00392A
Received 29 Apr 2010, Accepted 06 May 2010
First published online 24 May 2010

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Abstract
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A Zn-MOF assembled from a new C_2h-symmetric terphenyl dicarboxylate and DABCO was prepared and characterized by X-ray crystallography and gas sorption analysis: a preferential sorption of CO₂ over N₂ and H₂ was observed with an exceptionally high CO₂ adsorption enthalpy.

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Dalton Transactions

DABCO-functionalized metal–organic framework bearing a C_2h-symmetric terphenyl dicarboxylate linker

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