Issue 29, 2010

Encapsulation of cyclooctatetraenyl dianion in an unusual organic/inorganic lanthanide triple-decker sandwich complex

Abstract

Treatment of [(COT)Nd(THF)2(μ-Cl)]2 with dilithium tetraphenyldisiloxanediolate, (LiOSiPh2)2O, in a molar ratio of 1 : 4 afforded the novel organic/inorganic triple-decker complex (μ-η88-COT)[Nd{(Ph2SiO)2O}2{Li(THF)2}{Li(THF)}]2 (1) which was structurally characterized by X-ray diffraction.

Graphical abstract: Encapsulation of cyclooctatetraenyl dianion in an unusual organic/inorganic lanthanide triple-decker sandwich complex

Supplementary files

Article information

Article type
Communication
Submitted
09 Mar 2010
Accepted
01 Jun 2010
First published
14 Jun 2010

Dalton Trans., 2010,39, 6629-6631

Encapsulation of cyclooctatetraenyl dianion in an unusual organic/inorganic lanthanide triple-decker sandwich complex

V. Lorenz, S. Blaurock, C. G. Hrib and F. T. Edelmann, Dalton Trans., 2010, 39, 6629 DOI: 10.1039/C0DT00094A

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