Issue 16, 2010
From the journal:

Dalton Transactions

Tuning functional sites and thermal stability of mixed-linker MOFs based on MIL-53(Al)†

Stefan Marx,a   Wolfgang Kleist,*a   Jun Huang,a   Marek Maciejewskia  and  Alfons Baiker*a  

* Corresponding authors

a Department of Chemistry and Applied Biosciences, ETH Zurich, CH-8093 Zurich, Switzerland
E-mail: wolfgang.kleist@chem.ethz.ch, baiker@chem.ethz.ch
Fax: +41 44 63 21163

Abstract

The MIXMOF concept has been applied to the metal–organic framework compound MIL-53(Al). The random incorporation of two different linker molecules (benzene-1,4-dicarboxylate and 2-aminobenzene-1,4-dicarboxylate) in the framework structure and its influence on thermal stability were proven using several complementary techniques (XRD, ATR-IR, MAS-NMR and TG).

Graphical abstract: Tuning functional sites and thermal stability of mixed-linker MOFs based on MIL-53(Al)

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Article information

DOI
https://doi.org/10.1039/C002483J
Article type
Communication
Submitted
23 Dec 2009
Accepted
15 Feb 2010
First published
02 Mar 2010

Dalton Trans., 2010,39, 3795-3798

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Tuning functional sites and thermal stability of mixed-linker MOFs based on MIL-53(Al)

S. Marx, W. Kleist, J. Huang, M. Maciejewski and A. Baiker, Dalton Trans., 2010, 39, 3795 DOI: 10.1039/C002483J

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