Issue 13, 2010
From the journal:

Dalton Transactions

Chemical switching behaviour of tricarbonylrhenium(i) complexes of a new redox active ‘Pincer’ ligand†

Sarath Wanniarachchi,a   Brendan J. Liddle,a   John Toussaint,a   Sergey V. Lindeman,a   Brian Bennettb  and  James R. Gardinier*a  

* Corresponding authors

a Department of Chemistry, Marquette University, Milwaukee, WI, USA
E-mail: james.gardinier@marquette.edu
Fax: 414-288-7066
Tel: 414-288-3533

b Department of Biophysics, Medical College of Wisconsin, Milwaukee, WI, USA
E-mail: bbennett@mcw.edu
Fax: 414-456-6512
Tel: 414-456-4787

Abstract

The structures and optoelectronic properties of tricarbonylrhenium(I) complexes of di(2-pyrazolyl-p-tolyl)amine in its neutral and deprotonated (uninegative amido) form were investigated. Reactions of the complexes with Brønsted acids or bases result in distinctive changes of colour and electrochemical activity owing to the non-innocent nature of the ligand.

Graphical abstract: Chemical switching behaviour of tricarbonylrhenium(i) complexes of a new redox active ‘Pincer’ ligand

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Article information

DOI
https://doi.org/10.1039/C001344G
Article type
Communication
Submitted
05 Jan 2010
Accepted
26 Jan 2010
First published
12 Feb 2010

Dalton Trans., 2010,39, 3167-3169

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Chemical switching behaviour of tricarbonylrhenium(I) complexes of a new redox active ‘Pincer’ ligand

S. Wanniarachchi, B. J. Liddle, J. Toussaint, S. V. Lindeman, B. Bennett and J. R. Gardinier, Dalton Trans., 2010, 39, 3167 DOI: 10.1039/C001344G

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