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A missing high-spin molecule in the family of cyanido-bridged heptanuclear heterometal complexes, [(LCuII)6FeIII(CN)6]3+, and its CoIII and CrIII analogues, accompanied in the crystal by a novel octameric water cluster

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a
Inorganic Chemistry Laboratory, Faculty of Chemistry, University of Bucharest, Str. Dumbrava Rosie nr. 23, Romania
E-mail: marius.andruh@dnt.ro
b
Laboratory of Molecular Magnetism, Dipartimento di Chimica e UdR INSTM di Firenze, Università degli Studi di Firenze, Polo Scientifico, Via della Lastruccia 3, Sesto Fiorentino, Italy
c
Dipartimento di Fisica“A.Volta” e Unita’ CNISM-CNR, Universita’ di Pavia, Pavia, Italy
d
Department of Physics, Indian Institute of Technology Bombay, Powai, India
e
X-Ray Laboratory, Institute of Applied Physics, Academy of Sciences of Moldova, Str. Academiei nr. 5, Kishinev, Moldova
f
Institut Parisien de Chimie Moléculaire, UPMC and CNRS UMR7201, case courrier 42, UPMC-Paris 6, France
Dalton Trans., 2010,39, 4838-4847

DOI: 10.1039/B924505G
Received 23 Nov 2009, Accepted 17 Feb 2010
First published online 24 Mar 2010

This article is part of themed collection: Molecular magnets
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