Issue 6, 2010
From the journal:

Dalton Transactions

Extension of the charge separated-state lifetime by supramolecular association of a tetrathiafulvaleneelectron donor to a zinc/gold bisporphyrin†

Julien Boixel,a   Jérôme Fortage,a   Errol Blart,a   Yann Pellegrin,a   Leif Hammarström,*b   Hans-Christian Becker*b  and  Fabrice Odobel*a  

* Corresponding authors

a CEISAM, Chimie Et Interdisciplinarité, Synthèse, Analyse, Modélisation, CNRS, UMR CNRS 6230, UFR des Sciences et des Techniques 2, rue de la Houssinière - BP 92208, France
E-mail: Fabrice.Odobel@univ-nantes.fr

b Chemical Physics, Department of Photochemistry and Molecular Science, Uppsala University, Box 523, Sweden
E-mail: Leif@fotomol.uu.se

Abstract

Supramolecular triads were prepared by self-assembly of 4′-pyridyl-2-tetrathiafulvalene axially bound on ZnP-spacer-AuP+ dyads; the lifetime of the charge separated state (+TTF-ZnP-Spacer-AuP˙) formed upon light excitation of the triad is greatly increased with respect to that found in the parent dyad.

Graphical abstract: Extension of the charge separated-state lifetime by supramolecular association of a tetrathiafulvalene electron donor to a zinc/gold bisporphyrin

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Article information

DOI
https://doi.org/10.1039/B920079G
Article type
Communication
Submitted
02 Jul 2009
Accepted
10 Nov 2009
First published
27 Nov 2009

Dalton Trans., 2010,39, 1450-1452

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Extension of the charge separated-state lifetime by supramolecular association of a tetrathiafulvalene electron donor to a zinc/gold bisporphyrin

J. Boixel, J. Fortage, E. Blart, Y. Pellegrin, L. Hammarström, H. Becker and F. Odobel, Dalton Trans., 2010, 39, 1450 DOI: 10.1039/B920079G

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