Issue 46, 2009
From the journal:

Dalton Transactions

Spontaneous chiral resolution, nonlinear optical and luminescence of eight-coordinate lanthanide(III) complexes†

Hui-Fen Chen,a   Guo-Cong Guo,*a   Ming-Sheng Wang,a   Gang Xu,a   Wen-Qiang Zou,a   Sheng-Ping Guo,a   Mei-Feng Wua  and  Jin-Shun Huanga  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, P. R. China
E-mail: gcguo@fjirsm.ac.cn
Fax: 86 591 83714946

Abstract

The first eight-coordinated trivalent lanthanide complexes with an achiral ligand 6,7-dicyanodipyridoquinoxaline (dicnq), [DyCl3(dicnq)2]n (1 and 1′) were found to exhibit spontaneous chiral resolution, SHG active (two times that of KDP) and blue luminescence.

Graphical abstract: Spontaneous chiral resolution, nonlinear optical and luminescence of eight-coordinate lanthanide(III) complexes

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Article information

DOI
https://doi.org/10.1039/B917559H
Article type
Communication
Submitted
25 Aug 2009
Accepted
11 Sep 2009
First published
22 Sep 2009

Dalton Trans., 2009, 10166-10168

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Spontaneous chiral resolution, nonlinear optical and luminescence of eight-coordinate lanthanide(III) complexes

H. Chen, G. Guo, M. Wang, G. Xu, W. Zou, S. Guo, M. Wu and J. Huang, Dalton Trans., 2009, 10166 DOI: 10.1039/B917559H

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